Fig. 1 shows the neutralizing capacity of coals and coalashes. All twelve lignites (Samples 112, Table 1) required l 1 M H 2 SO 4 per kg coal, to establish a stable pH at liquid to solid ratio 10:1. The only asphaltite, Sample 13, used l/kg, mainly due to the high 'ash' percentage. We use a selected range of particle sizes, μm.
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The sintering and slagging of coal ash in the combustion chamber is mainly influenced by the melting point or ash fusion temperature (AFT) and the chemical contents of coal (Shi et al. 2021). The ...
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The Shell coal gasification process (SCGP) can operate on a wide variety of feedstocks. It consists of three principal stages: 1. Gasification (partial oxidation), in which the feedstock is converted to syngas in the presence of oxygen and a moderating agent (steam) in a refractorylined gasification reactor. 2.
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Song et al. reported that the AFT decreases with increasing CaO up to the concentration of 30%, above which increasing the CaO leads to an increase in the AFT. The result was attributed to the subliquidus phase transformation from anorthite to the gehlenite phase, increasing CaO by over 30%. ... The pyrolysis process of coal/biomass generally ...
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the formation of slaglayer protection during the process of lowAFT coal EFB gasification, and it might abate the generations of fouling and Analytical methods deposition on the tube surface in subsequent operation unit (, superheater) [44]. Thus, it might be anticipated that the additions of CS or The ...
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the process of pulverized coal combustion has been investigated in this paper. KEYWORDS. biomass, CC S, CFD, ... Federation. 160 364 391. Australia 144 818 14 301. China 138 819 39.
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the ash composition and its relation with AFT indicates Sialoferric nature of these coals. The corre ... coal industry. The AFT partially reflects the extent of ash agglomeration during coal conversion,, combustion, gasification, liquefaction, ... the process, the initial deformation temperature (IDT),hemisphericaltemperature(HT ...
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Formation of Coal (Process) Coal is composed of carbon, hydrogen, oxygen, nitrogen, sulphur, moisture, and incombustible mineral matter (, ash). Fluorinated gases are not formed by coal combustion. Coals are formed from the accumulation of vegetable debris in specialized environments. Obtaining coal from the mines is a difficult job.
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Introduction. Coal is used as main feedstock for South Africa's unique synfuels and petrochemicals industry. It is used by as a feedstock to produce synthesis gas (CO+H 2) via the Lurgi fixed bed dry bottom (FBDB) gasification plant located in Secunda gasify >30. million tons of bituminous coal to synthesis gas per year, which is converted to fuels and chemicals ...
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Coal ash fusion temperature (AFT) is one important parameter for coalfired boiler design and evaluation in a power plant. The relationship between coal AFT and the chemical composition of coal ash is rather complex in nature and makes the modeling of AFT difficult. In this work, a leastsquares support vector machine (LSSVM) model, which was based on a dynamically optimized search technique ...
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The leaching kinetics is characterized by a quick release of rare earth elements within the first few minutes of the process. For the West Kentucky No. 13 coal source, ∼75% of the REEs were leached in the first 15 min from the specific gravity (SG) fraction that was calcined at 600 °C. Additionally, the leaching kinetics of the ...
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The AFT calculation in the ammonia cofiring cases shared the same calculation method as above, depicted in Fig. S1 (b). The results showed that the AFT of the furnace in the base case was 2214 K. The coal feed rate, NH 3 feed rate, air feed rate, AFT, and EAC of different NH 3 cofiring ratio conditions under different scenarios are listed in ...
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Gasification of coal is a process whereby coal is converted to a syngas, which is predominately a mixture of carbon monoxide and hydrogen. ... The ash fusion temperature (AFT) is a common analysis performed on a coal sample as part of its routine characterisation, and can be a useful indicator of the general suitability of a specific coal for ...
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Ash fusion temperature (AFT) is an important index for coal gasification. A blend of fluxing agent with coal can decrease the AFT to meet the requirements of specific gasification process. Effect of alkaline oxide and silica alumina ratio on decreasing AFT is focused in this study. Simulation ash was used to investigate the effect of alkaline oxide on AFT. The experimental results showed that ...
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There are many types of specifications used to describe coal, these. include: Geological location, basin, seam, and rank. Physical heating value, size, moisture, ash, HGI, ash fusion temp. Chemical sulfur, ash chemistry, ultimate and trace elements. The key to the use of these specifications is to understand the.
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Coal is a solid, black, readily combustible fossil fuel that contains a large amount of carbonbased material approximately 50% of its weight. The formation of coal takes a significant amount of time (on the order of a few million years), and the first coalbearing rock units appeared about 290360 million years ago, at a time known as the Carboniferous or "coalbearing" Period.
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Sintering related temperatures. Sintering is an important process at the transition of ash to slag, which is predominantly initiated by the neck growth between ash particles and is shown in Fig. 12. Sintering of coal ash is a result of phases transformation in solid and liquid states.
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Gasification of coal is a process whereby coal is converted to a syngas, which is predominately a mixture of carbon monoxide and hydrogen. ... The AFT is a common analysis performed on a coal sample as part of its routine characterization and can be a useful indicator of the general suitability of a specific coal for entrainedflow gasification ...
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In Group 1, the content of Fe 2 O 3 and CaO are consistent as well as the sum of SiO 2 and Al 2 O 3. The S/A changes in the range of which covers the range of typical Chinese coal ashes. In Group 2, the total content of SiO 2 and Al 2 O 3 decreased to 70% and the content of CaO increased to 23%, correspondingly.
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This study aims to address the issues with repeatability by presenting a fully mechanised pellet production process and automated AFT process using a novel image analysis technique. Furthermore, for the first time, a wide range of pelleting methods will be directly compared, and an optimal preparation methodology has been identified. 2.
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Coal gasification fine slag (FS), a kind of byproduct of coal chemical industry, was recovered for the preparation of functional adsorbents by acid leaching process, which was orthogonally optimized by HCl, HNO3, HF, HAc, and H2SO4. Methylene blue () was used to evaluate the performance of functional adsorbents. The results demonstrated that % of the leaching efficiency (RLE) and ...
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Although the standard AFT analysis is currently used as prediction tool for AFT of coal, literature studies [1] have shown that this may not represent the actual flow temperature of certain minerals and mineral phases. For example iron (Fe) as Fe 2+ can react with other ash forming constituents leading to the formation of liquid phases at temperatures as low as 700 °C.
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This paper outlines research on the processes taking place within the coal mineral matter at high temperatures and development of the relationship between ash fusion temperatures (AFT) and phase equilibria of the coal ash slags. A new thermodynamic database for the AlCaFeOSi system developed by the author was used in conjunction with the thermodynamic computer package F ∗ A ∗ C ...
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Effect of coal nature on the gasification process. Mustafa Ozer, ... Badie Morsi, in Integrated Gasification Combined Cycle (IGCC) Technologies, 2017. Ash fusion temperature (melting temperature). AFT is an indicator of the ash melting behavior in the gasification process (Li, 2010).For the gasification of lowrank coals, such as lignite and brown coal, in fixed and fluidized beds ...
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To establish a simple method predicting ash fusion temperature (AFT) using FactSage calculation, the deformation temperature (DT) or flow temperature (FT) of coal ashes were measured by AFT analyzer and ash compositions were measured by Xray fluorescence spectrometry. The method to predict the DT and FT was proposed based on the liquidphase content and its variation trend with increasing ...
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Mining coal. Coal miners use large machines to remove coal from the earth. Many coal deposits, called coal beds or seams, are near the earth's surface, but others are deep mining methods allow coal miners to easily reach most of the nation's coal reserves and to produce about three times more coal in one hour than in 1978.
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This chapter deals with coal gasification, which is a process that converts carbonaceous materials, such as coal, petroleum, petroleum coke, or biomass, into carbon monoxide and hydrogen. ... The AFT of a coal can be manipulated by adding fluxes, such as limestone, or by blending with low ash fusion coals, thus decreasing the melting properties ...
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The AFT can be increased to >1350 °C by adding AFT increasing minerals or species, for example Al 2 O 3 or kaolinite, to the coal blend before it is fed into the gasification process. By increasing the AFT, the direct effect will be that steam consumption can be decreased, which in turn will improve carbon utilization.
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Coaldependent communities and the estimated 37,000 people working in coal power plants could benefit from the construction of advanced nuclear reactors. Benefits include the potential addition of more than 650 jobs, about 15% higher pay on average, and the ability for some of the existing workforce to transition without additional experience ...
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Coalification is the process by which peat is transformed into coal. The process of transforming vegetable matter into coal usually occurs in two main steps: the biochemical and the physicochemical stage of coalification ... Also significant for the use of coal is its Ash Fusion Temperature (AFT). The degree of fusion of ash is important in ...
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appetites for investments in new coal plants, and some have announced intentions to fully divest from coal assets within a few years (Polkinghorne 2017). The declining costs of Liquefied Natural Gas (LNG) could affect Indonesia's domestic energy mix and thus domestic coal demand, as it could replace coalfired electricity generation.
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