The different liquefaction mechanisms of lignite including free radical, oxidation, alkanolysis, and hydrogenation lead to the corresponding products: preasphaltene and asphaltene, mixed carboxylic acids, mixed esters and ethers, and cyclic compounds, respectively.
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Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the F. ( C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and ...
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A process for twostage catalytic hydrogenation and liquefaction of coal to produce increased yields of lowboiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a processderived liquid solvent and fed at temperature below about
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One of several direct liquefaction processes currently under advanced stages of development is the SolventRefined CoalI (SRCI) process. A major SRC1 product option is a low sulfur, low ash solid (SRC) which could be used as an electric utility boiler fuel much in the same manner that pulverized coal is currently fired in this type of combustion equipment.
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Gasification While the goal of combustion is to produce the maximum amount of heat possible by oxidizing all the combustible material, the goal of gasification is to convert most of the combustible solids into combustible gases such as carbon monoxide, hydrogen, and methane. Gasification reactions
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A process for liquefying a particulate coal feed to produce useful petroleumlike liquid products by steps which include: (a) contacting, in a liquefaction zone, said coal feed with a hydrogen donor solvent at temperature and pressure sufficient to hydroconvert and liquefy the coal, (b) separating the product from the liquefaction zone by distillation into fractions inclusive of a liquid ...
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An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogenrich gases at ...
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The principal direct liquefaction processes are: 1. Extraction. Some bioderived and waste materials yield an oil product by extraction that can directly be used as feed material for refining.
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The FischerTropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification.
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Abstract. The frontend design of a direct coal liquefaction process for the conversion of lignite into coal liquids by solvent extraction was investigated. The experimental work focused on ...
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(A) Schematic representation of elution zones of different chemical families representative of a coalderived middle distillate; (B) SFCFID chromatogram of a coalderived middle distillate using the pyridine bonded phase showing the huge resolution of phenols from hydrocarbons.
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Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA ...
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Also, you forgot about the power cost of 50 units of steam which is 1/8th of a brick of solid fuel or half a unit of coal (one unit of steam is 30KJ or, it takes 50 units of steam or to run a coal liquefaction cycle, which is /12 = units of solid fuel or /3 = units of coal).
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Coal Liquefaction is the process of converting coal to liquid fuels. What is Coal Liquefaction? The process of coal liquefaction creates synthetic liquid fuels from solid as substitutes for various petroleum products. There are two types of liquefaction direct and indirect .
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The direct coal liquefaction process usually produces a liquefaction residue of about 30% of its coal feed. The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significance for improving the oil yield of the direct liquefaction process and reducing the amount of pollution emitted from this oilcontaining organic solid waste. In ...
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A process for liquefying a particulate coal feed to produce useful petroleumlike liquid products which comprises contacting; in a series of two or more coal liquefaction zones, or stages, graded with respect to temperature, an admixture of a polar compound; or compounds, a hydrogen donor solvent and particulate coal, the total effluent being passed in each instance from a low temperature zone ...
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Liquefaction process is carried out in a low temperature typically at 250350°C and high H2 pressure in the range of 520 MPa, and a catalyst is used to assist the process to produce biooil [59]. This technique is very suitable for moisture feedstock like microalgae as it has very high water content (>80%) and no drying process is required [66].
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Coal liquefaction is the process of converting solid coal into liquid fuel. This process has been developed as a means to utilize coal resources that are otherwise difficult to access and transport. The resulting liquid fuel, called synthetic crude oil, can be refined into a variety of fuels, including diesel, gasoline, and aviation fuel.
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Petroleum gas production. For producing petroleum gas, the optimal advanced oil processing ratio is 20:5:17 (advanced oil processing : heavy oil cracking : light oil cracking), and 8:2:7 is close enough. Using coal liquefaction, the ratio is 60:39:55 (coal liquefaction : heavy oil cracking : light oil cracking), and 12:8:11 is close enough.
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Highlights. Coal liquefaction, the conversion of coal to a cleanburning, lowsulfurcontent fuel, is a technology that can augment petroleumderived products such as gasoline and boiler fuels and help meet the requirement for large supplies of liquid fuel. Direct liquefaction produces liquids through the interaction of coal and hydrogen at ...
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Fig. 12 shows the total costs of the whole coal liquefaction process together with the costs of four major parts: coal price, (coal) transportation, DCL production and distribution. Among three, "DCL_R" is the most economical one, the price of which is only two third of "DCL_H". For "DCL_H" and "DCL_R", the price caused by the ...
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The direct coal liquefaction process. usually produces a coal liquefaction residue (CLR) of about 30%. of its coal feed (Xu et al., 2014), and there is more than 80%. organic matter in the CLR ...
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On the surface, it looks pretty much the same as the process of coal liquefaction. It is a thermochemical conversion process of organic material into liquid biocrude and coproducts. Depending on the process, it is usually conducted under moderate temperatures (300400°C, lower than coal liquefaction) and pressures (1020 MPa, similar or ...
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An integrated coal pretreatment, liquefaction and gasification process is provided in which particulate coal is contacted with a vapor phase hydrogen donor solvent to swell the coal particles. The swollen coal particles are subjected to coal liquefaction conditions at relatively low temperatures.
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Plasmochemical hydrogenation of coal is a new process of direct production of acetylene and alkenes in the gaseous phase, in contrast to traditional processes of coal hydrogenation (liquefaction). Propanebutane mixture (50% C 3 H 8 +50% C 4 H 10), 200 t −1, is used as a hydrogenating agent instead of hydrogen, 2000 t −1.
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Coal Liquefaction It is an alternative route to produce diesel and gasoline and makes economic sense only in a world of high crude oil prices,Also called Coal to Liquid (CTL) technology. The process involves gasification of coal, which in turn will produce synthetic gas (a mix of CO+H2).
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misc{etde_609560, title = {Effect of catalyst addition on coliquefaction process of coal and biomass in supercritical water; Chorinkaisui wo mochiita sekitan biomass doji ekika process ni okeru shokubai tenka koka} author = {Yokura, H, Nonaka, H, Matsumura, Y, Tsutsumi, A, and Yoshida, K} abstractNote = {Mixture of coal and cellulose was liquefied in supercritical water (400degC, 25 MPa ...
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the process to dissolve the coal and to transfer externally produced hydrogen to the coal molecules. Catalytic liquefaction resembles solvent extraction, except that hydrogen is added to the coal with the aid of a catalyst. Figure presents the flow diagram of a typical solvent extraction or catalytic liquefaction plant. These coal ...
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The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FTIR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible ...
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Description Direct coal liquefaction involves contacting coal directly with a catalyst at elevated temperatures and pressures with added hydrogen (H 2 ), in the presence of a solvent to form a raw liquid product which is further refined into product liquid fuels.
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The Hcoal process is to be installed at a site in Kentucky and will have a 600 tons/day coal capacity, small compared to the coal gasification demonstration plants under study. The comparative lack of activity in coal liquefaction compared to gasification is the result of the factors described in Section VII,C .
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History. In the past, coal was converted to make coal gas, which was piped to customers to burn for illumination, heating, and cooking. High prices of oil and natural gas led to increased interest in "BTU Conversion" technologies such as gasification, methanation and liquefaction. The Synthetic Fuels Corporation was a governmentfunded corporation established in 1980 to create a market ...
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Indirect liquefaction of coal (ICL) has been found to be the most commercially viable process involving the gasification of coal. ICL includes two steps; in the first step, coal is converted into syngas ( Coal+H2OCO+H2), and during the last step, syngas is synthesized in the presence of a catalyst into liquid fuels.
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