XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave heating and conventional heating conditions. The effects of microwave fields on the molecular properties, bond strength and reaction kinetic of organic sulfurcontaining groups were studied by quantum chemical calculation.
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The desulfurization process of circulating fluidized bed desulfurization technology involves the injection of flue gas from the bottom of the fluidized bed through a Venturi tube. ... Microwave heating motivated performance promotion and kinetic study of iron oxide sorbent for coal gas desulfurization. Fuel, 267 (2020), Article 117215, ...
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Sulfur dioxide is the most important precursor of acid rain and one of the major contaminants generated from coalfired power plants. Currently, the limestonegypsum wet fluegas desulfurization (WFGD) system is the most widely used method for removal of SO 2 from powerplant exhaust fumes. However, the gypsum byproduct of limestonegypsum WFGD ...
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The flue gas desulfurization process in coalfired power plants is energy and resourceintensive but the ecoefficiency of this process has scarcely been considered. Given the fluctuating unit load and complex desulfurization mechanism, optimizing the desulfurization system based on the traditional mechanistic model poses a great challenge. In this regard, the present study optimized the eco ...
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This work was conducted through field tests on a coalfired circulating fluidized bed boiler with a condensation scrubber (CS) for flue gas waste heat recovery installed behind the wet flue gas desulfurization (WFGD) scrubber. Levels of multiple pollutants were investigated along the various flue gas devices of the boiler, with the CS being the ...
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Wet Desulfurization Technology (WFGD) is the main process for flue gas desulfurization in coalfired power plants in China, mainly including limestonegypsum wet method and seawater desulfurization. At the end of 2014, more than % of the desulfurization equipment was WFGD.
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The increasing use of highsulfur coal contradicts with the stringent environmental pressure in metallurgical industry. Microwave has been confirmed to have efficient effect for coal desulfurization. However, the removal behavior of thiophenic sulfur, as the most difficult sulfur to remove from coal, is still unclear in microwave field. In this work, the feasibility of removing thiophenic ...
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This study investigated the characteristics of mercury emitted from a largescale coalfired power plant in Taiwan via intensive sampling campaigns. The air pollution control devices equipped in this coalfired power plant include selective catalytic reduction, fabric filter and seawater flue gas desulfurization. During three sampling campaigns, mercury concentrations emitted from this large ...
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environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. T his work summarizes the desulfur ization and denitration
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Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Flue gas desulfurization systems have been used to limit the release of sulfur dioxide from coalfired power plants since the late 1960s, but in the past decade the production of FGDG has ...
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Mechanism of Pyrite Microbial Desulfurization. The oxidation process of coal conversion is possible by microorganisms after getting influenced by the polyfunctional coal structure and this process usually depends on two main factors: size or shape of coal and surface properties of microorganisms (Konishi et al. 1990). The morphology and ...
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The resultant products of this process,, (NH 4) 2 SO 4, can be recycled as fertilizers while reducing the discharge of solid or liquid waste. During the desulfurization process, many elements produced from the burned coal, such as metal ions, ash, fluoride, and chloride, are absorbed and accumulated in the desulfurization slurry.
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A large amount of SOx will be produced in the combustion process of coal without desulfurization, which is the main factor causing air pollution, environmental damage and increase.
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The present work describes the desulfurization of coal using mildly reductive method. Both a Yanzhou and a Yanshan coal (referred to as YZ and YS coal, respectively), were treated in an aqueous media employing sodium borohydride (NaBH 4) as reducing agent, which is a well known hydrogen variables investigated include concentration of reductant, time, pH of initial media ...
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In addition, the photocatalytic desulfurization process has little effect on the heat value of coal. On a basis of TGDSCDDSC analysis, it is found that the calorific value of the coal after photocatalytic desulfurization was slightly changed and the low temperature oxidation tendency was decreased which is helpful for desulfurized coal storage.
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Before and after the desulfurization process; total sulfur, pyritic sulfur, carbon content and calorific value were measured. The highest removal efficiencies of total sulfur and pyritic sulfur for Burdur coal obtained as 41% and 67%, for Tunçbilek coal obtained as 41% and 35%, and for Ermenek coal obtained as 47% and 41%, respectively.
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In this work, the desulfurization process of highsulfur anthracite coal is discussed, and the desulfurization method of "reduced iron powder + heat treatment + magnetic separation" (named "RIHM") is designed. ... In this study, a highsulfur coal desulfurization experiment was carried out for highsulfur raw coal to reveal the internal ...
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Most of the effective coal desulfurization techniques are based on chemical methods. Main desulfurization methods are chemical desulfurization, leaching, extraction, flotation, oxydesulfurization and biodesulfurization. The alkaline desulfurization is more effective in removing the pyritic sulfur from the coal, which is the less abundant form ...
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The coal hydrogen production process requires hightemperature steam as a reactant. Coalfired boilers are usually used to provide hightemperature steam. The ammoniabased desulphurization process is an effective technology to remove SO2 in the coalfired flue gas. However, the mass transfer coefficient of SO2 in such an engineered process is not readily available in the literature. In this ...
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The FlueGas Desulfurization (FGD) process utilizes a set of technologies to remove sulfur dioxide (SO 2) from the flue gas emissions of coalfired power systems were developed as a response to the exhaust flue gases from fossil fuelburning plants, principally coalburning, that posed both an environmental and human health hazard.
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This paper briefly introduces various methods of coal desulfurization (physical desulphurization, chemical desulfurization, biological desulfurization, etc.) and analyzes some problems existing in each method. The principle and research process of friction electrostatic separation technology and high gradient magnetic separation technology in precombustion desulfurization technology are ...
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The desulfurization process took place at a pH of 35, the coalparticle size was 7545 μm, the pulp density was 5%, the temperature was 35°C, and the incubation time was 8 h. Chemical studies also revealed a decrease in the ash content and an increase in the calorific value of coal from 6219 cal/g to 6406 and 6315 cal/g, which indicated ...
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The study aims to develop a thorough understanding of the desulfurization process and establish a theoretical framework for advancing clean coal technology and efficient coal utilization. Stringent control was maintained over parameters such as particle size, pretreatment time, bacterial species, and bacterial concentration.
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The main factor for the results above was that the desulfurization mechanisms were different. Therefore, the research of different desulfurization mechanisms is the main direction of future work. The consequence of this paper would provide data support for the selection of the desulfurization method for high sulfur coal.
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environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. This work summarizes the desulfurization and denitration ... In the wet desulfurization process, the scaling and blockage of equipment are easy to occur in the process site. In view of the above problems, a calciumsodium ...
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For future approaches, as well as desulfurization process, increasing the purity of coal may also promote the value of coal and prevent environment pollution. In the study of Etemadifar et al., growing and resting cells of heterotrophic Rhodococcus erythropolis strains PD1, R1, and FMF, and R. qingshengii were utilized in sulfur removal and ...
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Abstract To explore the feasibility of organic sulfur removal using organic acids, oxalic acid, citric acid and ascorbic acid were selected as desulfurization reagents. Combined with microwave irradiation technology, desulfurization experiments of highsulfur coal treated with nitric acid were conducted. The orthogonal experimental results showed that the microwave synergistic citric acid ...
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An effective precombustion coal desulfurization process should ideally be capable of removing both organic and inorganic sulfur. A variety of techniques exist for the removal of inorganic sulfur from coal, but there is currently no costeffective method for the precombustion removal of organic sulfur. Recent developments have demonstrated ...
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Pyrolysis desulfurization is suitable for coal. By changing the coking conditions to promote the effusion of sulfide in the form of gas. ... The high temperature, pressure and strong acid or alkali in traditional desulfurization process increase the hazards and bring secondary pollution. Essentially, desulfurization is a combination of ...
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When the consumed sulphur in coal is in the form of sulphur dioxide at the end of combustion, it reacts with water at high altitudes. Moreover, it goes down to the earth in the form of sulphuric acid, as well as damaging plants. The corrosive harmful impact on industrial plants is the removal of the sulphur in the coal when it is environmental.
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