A hightemperature reduction and smelting process was used to recover iron and calcium aluminate slag from highferrous bauxite.
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The solid addition of a calcium source, such as gypsum or bassanite avoids many of the complications mentioned thus far for 'inprocess' bauxite residue neutralisation, however it appears that the effectiveness of these compounds is compromised by encapsulation, requiring relatively higher dosages to be used.
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This study investigates the properties of H2reduced calciumadded bauxite residue, selfhardened pellets, and the feasibility of iron recovery through electrostatic and magnetic separation methods. The oxide pellets are prepared via a mixing of bauxite residue, calcite, and quicklime. The selfhardened pellets are reduced at 1000 °C with hydrogen gas flow for 120 min.
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Generally, 12 tons of bauxite residue generated while producing 1 ton of alumina mainly depending on the bauxite quality and production process (Zhao et al., 2009; Jones et al., 2012; Deihimi et al., 2018; Borra et al., 2015).According to the statistics of the International Aluminium Institute (Aluminium, 2019), Fig. 1 illustrated the world alumina production since the 21 st century and the ...
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The main minerals in the reduction product from the ironaluminum symbiotic ore obtained by the lowcalcium reduction process are Fe, NaAlO 2, Na 2 CaSiO 4 and NaAlSiO 4, and the iron metallization efficiency, the leaching efficiency of Al 2 O 3 and the content of iron in the concentrate are %, % and % respectively under the ...
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Data from alumina processing industry show an estimated global average production of bauxite residue (red mud) to be 1 to ton per ton of alumina, or about 150 million ton of red mud is produced annually. [ 1]
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The solution is clarified by filtering off the solid impurities, commonly with a rotary sand trap and with the aid of a flocculant such as starch, to remove the fine particles. The undissolved waste after the aluminium compounds are extracted, bauxite tailings, contains iron oxides, silica, calcia, titania and some unreacted alumina.
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He achieved this by using bauxite and lime as raw materials, and burning them together in a cupola furnace. Published by Rankin and Wright in 1915, the limealumina phase diagram demonstrates the presence of five calcium aluminate compounds—CA, CA 2, C 3 A, CA 6, and C1 2 A 7 .
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The Pedersen process was commercialized and is a high temperature (molten state) process that can separate iron and calcium aluminate slag . The method is regarded to be more material efficient and flexible in terms of the raw materials qualification to produce alumina as it can holistically utilize the bauxite or other alumina sources and ...
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The Ca content in most bauxite ores was below the detection limit except in India bauxite, which contained % Ca. Fig. C shows the XRD patterns of the four bauxite ores. The main crystalline Al phase in all bauxites was gibbsite, and an additional crystalline Fe phase (hematite) was detected in Ghana, India, and Guinea bauxites.
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This breakthrough has broadened the available bauxite reserves and effectively mitigated the harmful effects of SiO 2 during the Bayer leaching process while minimizing bauxite residue emissions. Calciumsilica slag (CSS) emerges as a solid residue generated during the chemical predesilication of medium and lowgrade bauxite.
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The alkaline release kinetics and response relationship of NA with respect to the process of bauxite residue neutralization were explored in this study. ... and C 1s to higher values were also found in the NA treated bauxite residue. Moreover, the calcium in the bauxite residue could react with NA to form "bridges" between organic matter ...
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This paper creates hydraulic binders using waste and a low energy input. Cements are produced with a bauxite refining residue (red mudRM), blended with limestone and lime, and fused at temperatures from 600 to 1200 °C. The Saudi RM investigated has significant Al and Si but low Ca. Therefore, lime (CaO) and limestone (CaCO3) are used, as a source of calcium, to harvest cementing hydrates ...
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A calcium aluminate (CA) slag of modelled composition, originating from the reductive smelting of Greek bauxite residue (BR) from the Aluminium of Greece facility, was hydrometallurgically treated ...
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The preparation process of highpurity PACl with calcium aluminum and bauxite is developed, and the production cost is lower than that of acid dissolving of aluminum hydroxide. The metal ions can be effectively removed from the liquid PACl solution at both room and high temperatures.
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Bauxite is the principal ore of aluminum. The first step in producing aluminum is to crush the bauxite and purify it using the Bayer Process. In the Bayer Process, the bauxite is washed in a hot solution of sodium hydroxide, which leaches aluminum from the bauxite. The aluminum is precipitated out of solution in the form of aluminum hydroxide ...
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Abstract Bauxite residue (red mud—RM), a byproduct of the Bayer process for refining bauxite to alumina, is highly alkaline (pH ∼ 13) and its treatment and storage poses unique waste management challenges. In this work, the acid neutralizing capacity (ANC) of Jamaican RM from a storage facility in Sherwin, Texas, was measured, and the solid and aqueous phase contributions to the ANC were ...
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A typical calcination process involves the conversion of calcium carbonate to calcium oxide. (begin{array}{l}CaCo^{3}overset{Delta h}{rightarrow} CaO+ Coend{array} ) ... Calcination of bauxite and gypsum involving the removal of water of crystallisation in the form of water vapour.
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Bauxite residue, or red mud (RM), is an alkaline sludge waste produced via the alumina extraction process in bauxite mines. Depending on the source of bauxite, this residue can be considered as a ...
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Bauxite is a mixture of minerals which contain, as well as impurities, different concentrations of hydrated aluminium oxides. Gibbsite (alumina trihydrate), boehmite, and diaspore (alumina monohydrates) are the main ore minerals. Bauxite is a highaluminiumcontent rock. That is the main ore that aluminium is mined from.
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Calcium oxide plays an important role in alumina production by binding SiO2 from aluminosilicate raw materials (bauxite, nepheline, kaolinite, etc.) in aluminumfree compounds. The efficiency of the hydrochemical technology depends on the activities of calcium oxide or its compounds introduced into the alkaline aluminosilicate slurry. In this paper, we considered the effects of different ...
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During the digestion process of the Bayer method, lithium and gallium in bauxite will enter into the sodium aluminate solution (Tang et al. 2020; Xu et al. 2018), which will return to the digestion process for recycling after the precipitation of aluminum hydroxide from the decomposition of crystal to a large amount of red mud discharge, most of the lithium and gallium in the ...
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In the lime sinter process the additive is a calcium salt (usually calcite — ... Based on the stability field of silica gel formation, a stepwise acid leaching process for bauxite residue is proposed to facilitate downstream processing of the critical metals. Extraction of scandium from bauxite residue by highpressure leaching in sulfuric ...
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