Abstract. The thermal effects of five coal types' pyrolysis processes at heating rates of 5, 10, 15, 20, and 30 °C/min in the temperature range of 301000 °C were systemically investigated by thermogravimetric differential scanning calorimetry degassing stage S2, the pyrolysis stage S3, and the polycondensation stage S4.
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For the coal pyrolysis process, unstable sulfur compounds will decompose, generate sulfur radicals and release as sulfurcontaining gases, this becomes the main pathway for sulfur removal. Coal properties, minerals and sulfur forms in coal, and pyrolysis conditions such as temperature, atmosphere, and the mass transfer, are the main factors ...
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More importantly, during the pyrolysis process of 3560 mesh coal, the largest amount of coalchar and the smallest amount of coaltar are not only obtained, but highquality syngas is also obtained. Through the characterization of coaltar, it is found that coaltar is mainly composed of aromatic compounds, and the content can reach more ...
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The chemical structure of coal consists of various covalent and noncovalent interactions, which is the basis of understanding the coal pyrolysis process. 26 Based on proximate analysis, ultimate analysis and 13 CNMR, Mo Zheng 27 constructed a molecular model of NMH coal and used it for ReaxFFMD simulation of pyrolysis tar product. The ...
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Coal is the primary energy source in China, and coal pyrolysis is considered an essential and efficient method for clean coal utilization. Three high arsenic coals collected from the southwestern Guizhou province of China were chosen in this study. Lowtemperature ashing plus Xray diffraction analysis (XRD) was used to identify the minerals in coals. The three coals were pyrolyzed in a tube ...
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the yield of pyrolysis products. Jiang et al. investigated an integrated process of coal pyrolysis with steam reforming of propane (CPSRP) to improve tar yield using Ni/Al2O3 as a reforming catalyst [15]. The results suggested that the CPSRP and the integrated coal pyrolysis with steam reforming of methane (CPSRM) or methane with a few propane
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INTRODUCTION. Pyrolysis is the key process in carbon nanomaterial synthesis [], bulk carbon production [5, 6], fabrication of carbonbased devices [], fuel generation from organic waste [] and molecule fragmentation for their analysis via gas chromatographymass spectroscopy (GCMS) [].Primary examples of the technologically significant carbon materials prepared via pyrolysis include ...
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However, in terms of process economy, the required capital cost for highpressure equipment in the liquefaction process makes it less attractive for the industries and persuades them to develop fast pyrolysis for biooil production [6, 128, 136, 137, 142, 143]. It is worth mentioning that the biooil per se is a low value energy carrier.
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This technology builds upon decades of experience with gasification of coal. Both approaches have the potential advantages of being relatively insensitive to feedstock type, both suffer from production of unwanted byproducts. ... Slow pyrolysis is a conventional pyrolysis process whereby the heating rate is kept slow (approximately oC/s ...
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Production of synthetic crude oil from coal using the Toscoal pyrolysis process. Conference Cortez, D; LaDelfa, C Proc., Intersoc. Energy Convers. Eng. Conf.; (United States) This paper presents the results of a recent feasibility study of the Toscoal process for recovering oil and gas from coal prior to combustion in power plants. Conceptual ...
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Pyrolysis is a thermochemical treatment of any organic (carbon based) product at particular temperatures range in the absence of oxygen. The study of pyrolysis includes the changes in chemical composition and characteristics of physical phase (Buratti et al. 2015).This process includes the decomposition of coal's organic structure and the releases of volatile matter up to 70% weight loss.
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The complexity of coal combustion has made more researchers divide the combustion process into two stages: pyrolysis and late combustion. Up to now, many studies have been done on transformation behavior of nitrogen during coal pyrolysis [16], [17] and occurrence state and content of nitrogen in coal [18] .
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The experimental results show that coal pyrolysis process can be roughly divided into four stages, namely the drying and dehydration stage S1, the degassing stage S2, the pyrolysis stage S3, and ...
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The breaking of chemical bonds is the fundamental process in pyrolysis. Coal pyrolysis is the first step in coal gasification and other chemical processes, and is the basic process in clean coal technologies. Coal pyrolysis is closely related to coal composition and structure. The molecular structure of coal can be clarified based on pyrolysis ...
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The copyrolysis process of coal and biomass was simulated using Aspen Plus V11 software. The reliability of the model was verified by comparing the distribution of copyrolysis products under different raw material ratios with the experimental and simulated values. At last, through the economic analysis of the investment in plant construction ...
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OVERVIEW OF COALTOLIQUIDS: A HISTORICAL PERSPECTIVE iii ACRONYMS AND ABBREVIATIONS bbl Barrel BP British Petroleum bpd Barrels per day CAER University of Kentucky Center for Applied Energy Research CCLP Chevron Coal Liquefaction Process CCS Carbon capture and storage CO Carbon monoxide CO 2 Carbon dioxide CPI OPECConsumer Price Index
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Pyrolysis, as a process technology, has received considerable attention from many researchers because it is an important intermediate stage in coal conversion. Reactions parameters as the ...
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Two wellknown products created by pyrolysis are a form of charcoal called biochar, created by heating wood, and coke (which is used as an industrial fuel and a heat shield), created by heating coal. Pyrolysis also produces condensable liquids (or tar) and noncondensable gases. Process
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Pyrolysis is the thermal decomposition process of coal, where the coal is heated in the absence of oxygen to produce carbonaceous char, oil, and combustible gases. Unlike combustion, the pyrolysis technology is an endothermic process, where thermal energy required driving off moisture and volatile matter ( Das et al., 2016 ).
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The pyrolysis of coal was the process of producing volatiles and coalchar in an inert atmosphere. When the pyrolysis temperature was low, the carbonization of coal particles was dominant, leading the high yield of coalchar. As the temperature further increased, the redecomposition of coalchar generating coalgas occurred, which resulted in ...
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aims to combine the conversion of biowaste and biomethanethrough innovative catalysed pyrolysis with chemical leaching, to fully convert biowaste into green hydrogen and biocoal, and recover critical (inorganic) raw materials. The result of the process is a material to be used in steelmaking as a substitute forfossil coke,
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Coal SJC, coal WJG, coal ZJM, and coal HCG were selected to investigate the pyrolysis kinetics of northern Shaanxi coals. TG and DSC experiments of four coals were carried out with a synchronous thermal analyzer at heating rates 5, 10, 15, and 20 C/min, respectively. The pyrolysis characteristics were described by thermogravimetric data, and the kinetic parameters were calculated by Flynn# ...
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The pyrolysis of pulverized coal takes only a few hundred milliseconds, and the coal combustion/pyrolysis process produces carbon black quickly. The formation of carbon black particles mainly includes their initial nucleation, growth process, fusion, and polymerization [7]. The coal tar generated by the primary pyrolysis of coal contains a ...
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The pyrolysis of different coal samples at different conditions indicated that product distribution and product composition were directly related to pyrolysis conditions and coal properties. By using an ordinary pyrolysis method, sulfur removal from coal is only 15% to 40%. Sulfur content in the char from DT, HLGL, PS, YZ or SF coal is lower ...
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Pyrolysis, which is the initial stage of the coal conversion process, is a significant approach to realize efficient coal resource utilization. Current research on the mechanism of the coal pyrolysis reaction primarily focuses on aspects such as the generation law of pyrolysis products [6], evolution characteristics of the chemical structure ...
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Therefore, proper pyrolysis mechanism model can optimize the copyrolysis process to reflect the actual copyrolysis interactions. This work is aimed to detect the primary volatiles from pyrolysis of lowrank coal and waste plastics using insitu PyTOFMS and to further reveal the interactions between coal and plastics based on the primary ...
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The purpose of this paper was to explore the relationship between the volatilization of arsenic and sulfur during the pyrolysis process. The study covered pyrolysis of three coals with different arsenic and sulfur contents under different temperatures. The mode of occurrence of sulfur and arsenic in coal were determined respectively.
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Coal pyrolysis refers to a series of physical and chemical changes that occur when coal is heated under an isolated atmosphere or inert atmosphere. The organic matter in coal can be pyrolyzed to produce char, tar, and gas. The chemical process of coal pyrolysis is very complicated, mainly involving bond breaking, vaporization, and polyreaction.
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The thermal effects of five coal types' pyrolysis processes at heating rates of 5, 10, 15, 20, and 30 °C/min in the temperature range of 301000 °C were systemically investigated by thermogravimetric differential scanning experimental results show that coal pyrolysis process can be roughly divided into four stages, namely the drying and dehydration stage S1, the degassing ...
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Depolymerization of coal increases the tar yield in coal pyrolysis and enhances the thermoplasticity of the coal, which makes coal more favorable for producing coke and other valueadded products like graphite electrodes, carbon fiber, aromatic chemicals, etc. In this study, the authors have proposed a novel coal depolymerization method that combines the oxidation reactions by molecular oxygen ...
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The heterogeneous nature of coal and the complexity of the pyrolysis process have made it very difficult to perform unambiguous experiments to determine the rates and mechanisms in coal pyrolysis. However, recent years have seen a number of new experimental and theoretical approaches which shed new light on the subject. This paper considers the recent progress on kinetics, the formation of ...
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Pyrolysis polygeneration technology is a good way to realize clean and efficient utilization of lowrank coal and heat carrier is a key factor. Aspen Plus is used to establish lowrank coal pyrolysis staged conversion polygeneration technology with semicoke heat carrier based on dualfluidized bed (CPSCPCDFB), which couples with ultrasupercritical semicoke powder furnace for power generation.
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1. Introduction Pyrolysis is an effective and mild coal conversion process. The polygeneration technology based on coal pyrolysis can produce many valuable products such as highcalorific pyrolysis gas, upgraded coal tar, and clean solid fuel char or coke, which will realize multilevel efficient utilization of coal resources. 1,2 The products of coal pyrolysis are affected by various factors ...
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Coal pyrolysis is a critical step of coal thermal conversion, impacting the downstream utilisation of coal, such as combustion and gasification. The understanding of this complex process plays a crucial role to predict the products, operation optimisation and reactor design. Indian coals typically have 2552% (as received) ash yields.
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